Prediction of electropolymerization mechanisms of two substituted phenylene: Poly-3-methoxy-toluenes (P3mt1 and P3mt2)

Ayachi, S. and Bouzakraoui, S. and Hamidi, M. and Bouachrine, M. and Molinié, P. and Alimi, K. (2006) Prediction of electropolymerization mechanisms of two substituted phenylene: Poly-3-methoxy-toluenes (P3mt1 and P3mt2). Journal of Applied Polymer Science, 100 (1). pp. 57-64.

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Abstract

P3mt1 and P3mt2 were electrochemically synthesized using two different electrolyte supports H2SO4 and TEABF4, respectively. First, it was deduced from density functional theory (DFT) calculations that the electronic and steric effects govern polymerization mechanism of the radical monomers. Second, DFT combined with experimental spectroscopic analyses (ESR, Infrared, Raman, and 13C NMR) demonstrate that H2SO4 or TEABF4 could generate a homogenous or heterogeneous coupling site, respectively. © 2006 Wiley Periodicals, Inc.

Item Type:	Article
Uncontrolled Keywords:	Electrolytes; Electropolymerization; Infrared spectroscopy; Monomers; Probability density function; Raman spectroscopy; Spectroscopic analysis; Synthesis (chemical); Toluene, Experimental spectroscopic analyses (ESR); Radical polymerization; Spin density; Structure-property relations, Aromatic compounds, electrochemistry; polymer; polymerization; Raman spectroscopy; synthesis
Subjects:	Chemistry
Divisions:	SCIENTIFIC PRODUCTION > Chemistry
Depositing User:	Administrateur Eprints Administrateur Eprints
Last Modified:	31 Jan 2020 15:45
URI:	http://eprints.umi.ac.ma/id/eprint/2047

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