Bih, L. and Abbas, L. and Nadiri, A. and Khemakhem, H. and Elouadi, B. (2008) Investigations of molybdenum redox phenomenon in Li2O-MoO3-P2O5 phosphate glasses. Journal of Molecular Structure, 872 (1). pp. 1-9.

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Abstract

Two series of glasses have been prepared and characterized. One with varying Li2O/P2O5 ratio and the other with varying Mo/P ratio. The relationship between the formation of the reduced state of molybdenum in phosphate glasses and the type of gases released in heating batch materials has been investigated. Effect of temperature on the valence state of molybdenum is also studied. Oxidation-reduction (redox) equilibrium of Mo5+/Mo6+ and environment of molybdenum (V) in these series of lithium-molybdenum-phosphate glasses are related to the glass composition and the possible structural units formation in the glasses. © 2007 Elsevier B.V. All rights reserved.

Item Type: Article
Uncontrolled Keywords: Glass; Lithium compounds; Paramagnetic resonance; Phosphates; Redox reactions, Glass composition; Molybdenum oxides; Phosphate glasses; Redox phenomenon, Molybdenum compounds
Subjects: Chemistry
Divisions: SCIENTIFIC PRODUCTION > Chemistry
Depositing User: Administrateur Eprints Administrateur Eprints
Last Modified: 31 Jan 2020 15:45
URI: http://eprints.umi.ac.ma/id/eprint/2033

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