Almadori, Y. and Alvarez, L. and Le Parc, R. and Aznar, R. and Fossard, F. and Loiseau, A. and Jousselme, B. and Campidelli, S. and Hermet, P. and Belhboub, A. and Rahmani, A. and Saito, T. and Bantignies, J.-L. (2014) Chromophore ordering by confinement into carbon nanotubes. Journal of Physical Chemistry C, 118 (33). pp. 19462-19468.

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We report an experimental study on the confinement of oligothiophene derivatives into single-walled carbon nanotubes over a large range of diameter (from 0.68 to 1.93 nm). We evidence by means of Raman spectroscopy and transmission electron microscopy that the supramolecular organizations of the confined oligothiophenes depend on the nanocontainer size. The Raman radial breathing mode frequency is shown to be monitored by both the number of confined molecules into a nanotube section and the competition between oligothiophene/oligothiophene and oligothiophene/tube wall interactions. We finally propose simple Raman criteria to characterize oligothiophene supramolecular organization at the nanoscale. © 2014 American Chemical Society.

Item Type: Article
Uncontrolled Keywords: Single-walled carbon nanotubes (SWCN); Supramolecular chemistry; Transmission electron microscopy, Confined molecules; Nano scale; Nanocontainers; Oligothiophene derivative; Oligothiophenes; Radial breathing mode; Supramolecular organizations, Chromophores
Subjects: Chemistry
Divisions: SCIENTIFIC PRODUCTION > Chemistry
Depositing User: Administrateur Eprints Administrateur Eprints
Last Modified: 31 Jan 2020 15:45

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